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Multicomponent thin films with spectral hole burning capacity at room temperature were synthesized by using molecular beam and pulsed laser deposition techniques All materials were activated by Sm2+ in low-symmetry alkaline earth sites, the synthesis involved the control of ionic diffiision rate during multilayer growth and special reduction of Samarium. Enhancement of hole burning rate by 1-2 orders is obtained in nanocrystalline films as compared to bulk and microcrystalline materials New hypothetic mechanism involving the creation of Sm-defect (photochromic) centers is proposed for reversible photoburning. |